Introduction to Polymer Chemistry (3^rd Ed.)

Continuing the tradition of its previous editions, the third edition of Introduction to Polymer Chemistry provides a well-rounded presentation of the principles and applications of natural, synthetic, inorganic, and organic polymers. With an emphasis on the environment and green chemistry and materials, this third edition offers detailed coverage of natural and synthetic giant molecules, inorganic and organic polymers, biomacromolecules, elastomers, adhesives, coatings, fibers, plastics, blends, caulks, composites, and ceramics.

Using simple fundamentals, the book demonstrates how the basic principles of one polymer group can be applied to all of the other groups. It covers reactivities, synthesis and polymerization reactions, techniques for characterization and analysis, energy absorption and thermal conductivity, physical and optical properties, and practical applications. This edition addresses environmental concerns and green polymeric materials, including biodegradable polymers and microorganisms for synthesizing materials. Case studies woven within the text illustrate various developments and the societal and scientific contexts in which these changes occurred.

Now including new material on environmental science, Introduction to Polymer Chemistry, Third Edition remains the premier book for understanding the behavior of polymers. Building on undergraduate work in foundational courses, the text fulfills the American Chemical Society Committee on Professional Training (ACS CPT) in-depth course requirement.

Introduction to Polymers
. History of Polymers
. Why Polymers?
. Today’s Marketplace
. Environmental Assessment
. Managing Sustainability
. General Encyclopedias and Dictionaries

Polymer Structure (Morphology)
. Stereochemistry of Polymers
. Molecular Interactions
. Polymer Crystals
. Amorphous Bulk State
. Polymer Structure–Property Relationships
. Crystalline and Amorphous Combinations
. Crosslinking

Molecular Weight of Polymers
. Introduction
. Solubility
. Average Molecular Weight Values
. Fractionation of Polydisperse Systems
. Chromatography
. Colligative Molecular Weights
. Light-Scattering Photometry
. Other Techniques
. Viscometry

Naturally Occurring Polymers
. Polysaccharides
. Cellulose
. Cellulose-Regenerating Processes
. Esters and Ethers of Cellulose
. Starch
. Other Polysaccharides
. Proteins
. Nucleic Acids
. Naturally Occurring Polyisoprenes and Other Synthetic Elastomers
. Lignin
. Melanins
. Polymer Structure
. Genetic Engineering
. NA Profiling
. Asphalt

Step-Reaction Polymerization (Polycondensation Reactions)
. Comparison between Polymer Type and Kinetics of Polymerization
. Introduction
. Stepwise Kinetics
. Polycondensation Mechanisms
. Polyesters and Polycarbonates
. Synthetic Polyamides
. Polyimides
. Polybenzimidazoles and Related Polymers
. Polyurethanes and Polyureas
. Polysulfides
. Polyethers
. Polysulfones
. Poly(Ether Ether Ketone) and Polyketones
. Phenolic and Amino Plastics
. Synthetic Routes
. Liquid Crystals
. Microfibers

Ionic Chain-Reaction and Complex Coordination Polymerization (Addition Polymerization)
. Cationic Polymerization
. Anionic Polymerization
. Stereoregularity and Stereogeometry
. Polymerization with Complex Coordination Catalysts
. Soluble Stereoregulating Catalysis
. Polyethylenes
. Polypropylene
. Polymers from 1,4-Dienes
. Polyisobutylene
. Metathesis Reactions
. Zwitterionic Polymerization
. Isomerization Polymerization
. Precipitation Polymerization

Free Radical Chain Polymerization (Addition Polymerization)
. Initiators for Free Radical Chain Polymerization
. Mechanism for Free Radical Chain Polymerization
. Chain Transfer
. Polymerization Techniques
. Fluorine-Containing Polymers
. Polystyrene
. Poly(Vinyl Chloride)
. Poly(Methyl Methacrylate)
. Polyacrylonitrile
. Solid-State Irradiation Polymerization
. Plasma Polymerizations

Copolymerization
. Kinetics of Copolymerization
. The Q-e Scheme
. Commercial Copolymers
. Block Copolymers
. Graft Copolymers
. Elastomers
. Blends
. Polymer Mixtures: IPNS and Alloys
. Dendrites
. Ionomers
. Fluoroelastomers
. Nitrile Rubber
. Acrylonitrile Butadiene Styrene Terpolymers
. EPDM Rubber

Organometallic and Metalloid Polymers
. Introduction
. Inorganic Reaction Mechanisms
. Condensation Organometallic Polymers
. Coordination Polymers
. Addition Polymers

Inorganic Polymers
. Introduction
. Portland Cement
. Other Cements
. Silicates
. Silicon Dioxide (Amorphous)
. Sol–Gel
. Silicon Dioxide (Crystalline Forms): Quartz Forms
. Silicon Dioxide in Electronic Chips
. Asbestos
. Fly Ash and Aluminosilicates
. Polymeric Carbon: Diamond
. Polymeric Carbon: Graphite
. Internal Cyclization: Carbon Fibers and Related Materials
. Carbon Nanotubes
. Bitumens
. Carbon Black
. Polysulfur
. Ceramics
. High-Temperature Superconductors
. Zeolites

Reactions of Polymers
. Reactions with Polyolefins and Polyenes
. Reactions of Aromatic and Aliphatic Pendant Groups
. Degradation
. Cross-Linking
. Reactivities of End Groups
. Supramolecules and Self-Assembly
. Transfer and Retention of Oxygen
. Nature’s Macromolecular Catalysts
. Photosynthesis
. Mechanisms of Energy Physical Absorption
. Breakage of Polymeric Materials

Testing and Spectrometric Characterization of Polymers
. Spectronic Characterization of Polymers
. Surface Characterization
. Amorphous Region Determinations
. Thermal Analysis
. Thermal Property Tests
. Flammability
. Electrical Properties: Theory
. Electric Measurements
. Weatherability
. Optical Properties Tests
. Chemical Resistance

Rheology and Physical Tests
. Rheology
. Typical Stress–Strain Behavior
. Stress–Strain Relationships
. Specific Physical Tests

Additives
. Fillers
. Reinforcements
. Nanocomposites
. Plasticizers
. Antioxidants
. Heat Stabilizers
. Ultraviolet Stabilizers
. Flame Retardants
. Colorants
. Curing Agents
. Antistatic Agents: Antistats
. Chemical Blowing Agents
. Compatibilizers
. Impact Modifiers
. Processing Aids
. Lubricants
. Microorganism Inhibitors

Synthesis of Reactants and Intermediates for Polymers
. Monomer Synthesis from Basic Feedstocks
. Reactants for Step-Reaction Polymerization
. Synthesis of Vinyl Monomers

Polymer Technology
. Polymer Processing
. Secondary Structures: Mesophases
. Fibers
. Elastomers
. Films and Sheets
. Polymeric Foams
. Reinforced Plastics (Composites) and Laminates
. Molding
. Casting
. Extrusion
. Coatings
. Adhesives
. Conductive Polymeric Materials
. Drug Design and Activity
. Synthetic Biomedical Polymers
. Dental Materials
. Emerging Polymers
. Green Materials

Appendices
. Structures of Common Polymers
. Symbols
. Comments on Health and Toxicological Aspects of Polymers
. ISO 9000 and 14000
. Web Resources