Biomimetic Dye Aggregate Solar Cells, 2013 Springer Theses Series

This thesis describes a new approach to the construction of solar cells. Following nature's example, this approach has the goal to find a biomimetic self-assembling dye, whose aggregates can mimic the natural light-harvesting system of special photosynthetic active bacteria. The thesis investigates methods to control the self-assembly such that suitable dye aggregates are formed with high internal order and size-confinement. The dye aggregates can be implemented into a new type of solar cells, designed to combine the advantages of hybrid solar cells and solid-state dye-sensitized solar cells (ss-DSSCs): dye aggregate solar cells (DASCs). This book describes the construction and first tests of a prototype for DASCs on the basis of the investigated dye aggregates. The described approach has the advantage that it will enable to build up a light-harvesting system fully synthetically in large scale in order to realize low-cost, light-weight and environmentally friendly solar cells - a worthwhile goal towards the exploitation of clean energy from sunlight.

Theory and Literature Survey: Biomimetic Light-Harvesting.- Controlling the Self-Assembly of Zinc Porphyrin P2.- Conclusion: Biomimetic Light-Harvesting.- Theory and Literature Survey: Application of BLH to Solar Cells.- Construction of Solar Cells.- Results and Discussion: Application of BLH to Solar Cells.- Conclusion: Application of BLH to Solar Cells.

Nominated by the Technical University of Darmstadt (Germany) as an outstanding PhD thesis Exploits new ways to self-assembling dye aggregates for solar cells Develops a new solar cell prototype on the basis of the dye aggregates: dye aggregate solar cells (DASCs) Includes supplementary material: sn.pub/extras